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Accessibility information
Author(s):   O'Neal, H.E.; Benson, S.W.
Title:   Kinetics of the reaction between acetyl iodide and HI and the heat of formation of the acetyl radical
Journal:   J. Chem. Phys.
Volume:   37
Year:   1962
Reference type:   Journal article
Squib:   1962ONE/BEN540

Reaction:   CH3CO + HICH3CHO + I
Reaction order:   2
Reference reaction:   CH3CO + I2CH3C(O)I + I
Reference reaction order:   2
Temperature:   495 - 541 K
Pressure:  0.11 bar
Rate expression:   3.4x10-1 e-6269 [J/mole]/RT
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
495 7.41E-2
500 7.53E-2
525 8.09E-2
541 8.44E-2