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Author(s):   Taylor, R.; Smith, G.G.; Wetzel, W.H.
Title:   Substituent effects in pyrolysis. V. A p-σ+ correlation in the pyrolysis of 1-arylethyl acetates
Journal:   J. Am. Chem. Soc.
Volume:   84
Page(s):   4817 - 4824
Year:   1962
Reference type:   Journal article
Squib:   1962TAY/SMI4817-4824

Reaction:   Benzenemethanol, α,4-dimethyl-, acetate → CH3C(O)OH + 4-Methylstyrene
Reaction order:   1
Temperature:   585 - 637 K
Pressure:  8.00E-3 - 0.27 bar
Rate expression:   7.06x1012 [s-1] e-181255 [J/mole]/RT
Bath gas:   Benzenemethanol, α,4-dimethyl-, acetate
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
585 4.62E-4
600 1.17E-3
625 5.02E-3
637 9.68E-3