Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Chiltz, G.; Eckling, R.; Goldfinger, P.; Huybrechts, G.; Johnson, H.S.; Meyers, L.; Verbeke, G.
Title:   Kinetic isotope effect in photochlorination of H2, CH4, CHCl3, and C2H6
Journal:   J. Chem. Phys.
Volume:   38
Year:   1963
Reference type:   Journal article
Squib:   1963CHI/ECK1053

Reaction:   CHCl3 + Cl·CCl3 + HCl
Reaction order:   2
Reference reaction:   D2 + ClDCl + D
Reference reaction order:   2
Temperature:   382 - 476 K
Rate expression:   1.92±3.5x10-1
Bath gas:   CCl3D
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.