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Accessibility information
Author(s):   Hauser, W.P.; Walters, W.D.
Title:   The kinetics of the thermal isomerization of cyclobutene
Journal:   J. Phys. Chem.
Volume:   67
Page(s):   1328 - 1333
Year:   1963
Reference type:   Journal article
Squib:   1963HAU/WAL1328-1333

Reaction:   Cyclobutene1,3-Butadiene
Reaction order:   1
Temperature:   403 - 448 K
Pressure:  1.33E-4 - 4.27E-2 bar
Rate expression:   1.8x1013 [±1.1x1012 s-1] e-137189 [J/mole]/RT
Bath gas:   Cyclobutene
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
403 2.98E-5
425 2.48E-4
448 1.82E-3