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Accessibility information
Author(s):   Hautecloque, S.
Title:   Reaction des radicaux CCl.3 avec la molecule H2
Journal:   C.R. Acad. Sc. Paris
Volume:   257
Year:   1963
Reference type:   Journal article
Squib:   1963HAU131

Reaction:   H2 + ·CCl3CHCl3 +
Reaction order:   2
Reference reaction:   ·CCl3 + ·CCl3CCl3CCl3
Temperature:   521 - 575 K
Rate expression:   6.14x10-14 [cm3/molecule s] e-47309 [±1896 J/mole]/RT
Bath gas:   CCl3Br
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
521 1.11E-18
525 1.21E-18
550 1.97E-18
575 3.10E-18