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©NIST, 2013
Accessibility information
Author(s):   Holroyd, R.A.; Klein, G.W.
Title:   Mercury-photosensitized decomposition of aliphatic hydrocarbons-radical detection with ethyl-carbon-14 radicals
Journal:   J. Phys. Chem.
Volume:   67
Page(s):  
Year:   1963
Reference type:   Journal article
Squib:   1963HOL/KLE2273

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1963HOL/KLE2273   C3H8 + → Other Products + H2  298   1.90E-03           1.90E-03  2
  Reference reaction:  C2H4 + ·C2H5 2
  1963HOL/KLE2273   iso-C4H10 + → Other Products + H2  298   8.59E-03           8.59E-03  2
  Reference reaction:  C2H4 + ·C2H5 2
  1963HOL/KLE2273   (CH3)3CCH2CH3 + → Other Products + H2  298   1.80E-03           1.80E-03  2
  Reference reaction:  C2H4 + ·C2H5 2
  1963HOL/KLE2273   iso-C5H12 + → Other Products + H2  298   0.01           0.01  2
  Reference reaction:  C2H4 + ·C2H5 2
  1963HOL/KLE2273   (CH3)2CHCH(CH3)2 + → Other Products + H2  298   0.02           0.02  2
  Reference reaction:  C2H4 + ·C2H5 2
  1963HOL/KLE2273   (CH3)2CH(CH2)2CH3 + → Other Products + H2  298   0.01           0.01  2
  Reference reaction:  C2H4 + ·C2H5 2
  1963HOL/KLE2273   n-C5H12 + → Other Products + H2  298   3.70E-03           3.70E-03  2
  Reference reaction:  C2H4 + ·C2H5 2
  1963HOL/KLE2273   n-C8H18 + → Other Products + H2  298   3.70E-03           3.70E-03  2
  Reference reaction:  C2H4 + ·C2H5 2
  1963HOL/KLE2273   tert-C4H9 + ·C2H5C2H6 + iso-C4H8  298   0.54           0.54  2
  Reference reaction:  tert-C4H9 + ·C2H5(CH3)3CCH2CH3 2
  1963HOL/KLE2273   iso-C3H7 + ·C2H5C2H6 + CH3CH=CH2  298   0.21           0.21  2
  Reference reaction:  iso-C3H7 + ·C2H5iso-C5H12 2
  1963HOL/KLE2273   ·C2H5 + sec-C4H9 → Other Products + C2H6  298   0.23           0.23  2
  Reference reaction:  ·C2H5 + sec-C4H9(C2H5)2CHCH3 2
  1963HOL/KLE2273   ·C2H5 + CH3CH2CH2CHCH3 → Other Products + C2H6  298   0.25           0.25  2
  Reference reaction:  ·C2H5 + CH3CH2CH2CHCH3CH3(CH2)2CH(CH3)CH2CH3 2
  1963HOL/KLE2273   ·C2H5 + 2-hexyl radical → Other Products + C2H6  298   0.27           0.27  2
  Reference reaction:  ·C2H5 + 2-hexyl radicalHeptane, 3-methyl- 2
  1963HOL/KLE2273   ·C2H5 + (CH3)3CCH2 → Other Products + C2H6  298   0.60           0.60  2
  Reference reaction:  ·C2H5 + (CH3)3CCH2Pentane, 2,2-dimethyl- 2
  1963HOL/KLE2273   ·C2H5 + CyclopentylC2H6 + Cyclopentene  298   0.27           0.27  2
  Reference reaction:  ·C2H5 + CyclopentylCyclopentane, ethyl- 2
  1963HOL/KLE2273   ·C2H5 + (C2H5)2(CH3)C → Other Products + C2H6  298   0.80           0.80  2
  Reference reaction:  ·C2H5 + (C2H5)2(CH3)C → Other Products + C2H6 2
  1963HOL/KLE2273   ·C2H5 + (C2H5)2(CH3)C → C2H6 + (C2H5)2C=CH2  298   0.80           0.80  2
  Reference reaction:  ·C2H5 + (C2H5)2(CH3)C → Pentane, 3-ethyl-3-methyl 2
  1963HOL/KLE2273   ·C2H5 + (CH3)3CC(·)H(CH3) → Other Products + C2H6  298   0.20           0.20  2
  Reference reaction:  ·C2H5 + (CH3)3CC(·)H(CH3) → (CH3)3CCH(CH3)CH2CH3 2
  1963HOL/KLE2273   ·C2H5 + n-C3H7C(CH3)2C2H6 + C2H5CH2C(CH3)=CH2  298   0.74           0.74  2
  Reference reaction:  ·C2H5 + n-C3H7C(CH3)2Hexane,-3,3-dimethyl- 2
  1963HOL/KLE2273   ·C2H5 + (CH3)2CHC(·)(CH3)2 → C2H6 + (CH3)2C=C(CH3)2  298   0.72           0.72  2
  Reference reaction:  ·C2H5 + (CH3)2CHC(·)(CH3)2 → C2H5C(CH3)2CH(CH3)2 2

Search returned 20 records.