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Author(s):   Holroyd, R.A.; Klein, G.W.
Title:   Mercury-photosensitized decomposition of aliphatic hydrocarbons-radical detection with ethyl-carbon-14 radicals
Journal:   J. Phys. Chem.
Volume:   67
Year:   1963
Reference type:   Journal article
Squib:   1963HOL/KLE2273

Reaction:   tert-C4H9 + ·C2H5C2H6 + iso-C4H8
Reaction order:   2
Reference reaction:   tert-C4H9 + ·C2H5(CH3)3CCH2CH3
Reference reaction order:   2
Temperature:   298 K
Pressure:  7.33E-2 - 0.57 bar
Rate expression:   5.4x10-1±1.1x10-2
Bath gas:   iso-C4H10
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Sensitized photolysis
Analytical technique:   Gas chromatography

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