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Accessibility information
Author(s):   Smith, G.G.; Jones, D.A.K.; Brown, D.F.
Title:   Pyrolysis studies. VII. Rates of thermal decomposition of substituted ethyl benzoates
Journal:   J. Org. Chem.
Volume:   28
Page(s):   403 - 405
Year:   1963
Reference type:   Journal article
Squib:   1963SMI/JON403-405

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1963SMI/JON403-405   Ethyl benzoateBenzoic acid + C2H4  687   1.97E-03              1
  1963SMI/JON403-405   Benzoic acid, 4-methyl-, ethyl esterC2H4 + 4-Methylbenzoic acid  687   1.74E-03              1
  1963SMI/JON403-405   Benzoic acid, 4-methyl-, ethyl esterC2H4 + 4-Methylbenzoic acid  788   1.03              1
  Reference reaction:  Ethyl benzoateBenzoic acid + C2H4 1
  1963SMI/JON403-405   Benzoic acid, 4-amino-, ethyl esterC2H4 + 4-Aminobenzoic acid  788   0.86              1
  Reference reaction:  Ethyl benzoateBenzoic acid + C2H4 1
  1963SMI/JON403-405   Benzoic acid, 4-methoxy-, ethyl esterC2H4 + 4-Methoxybenzoic acid  788   0.96              1
  Reference reaction:  Ethyl benzoateBenzoic acid + C2H4 1
  1963SMI/JON403-405   Benzoic acid, 4-nitro-, ethyl ester4-Nitrobenzoic acid + C2H4  788   1.42              1
  Reference reaction:  Ethyl benzoateBenzoic acid + C2H4 1
  1963SMI/JON403-405   Benzoic acid, 3-methyl-, ethyl esterC2H4 + 3-Methylbenzoic acid  687   2.12E-03              1
  1963SMI/JON403-405   Benzoic acid, 3-methyl-, ethyl esterC2H4 + 3-Methylbenzoic acid  788   1.08              1
  Reference reaction:  Ethyl benzoateBenzoic acid + C2H4 1
  1963SMI/JON403-405   Benzoic acid, 4-hydroxy-, ethyl esterC2H4 + Benzoic acid, 4-hydroxy-  788   0.91              1
  Reference reaction:  Ethyl benzoateBenzoic acid + C2H4 1
  1963SMI/JON403-405   Benzoic acid, 3-amino-, ethyl esterC2H4 + 3-Aminobenzoic acid  788   1.01              1
  Reference reaction:  Ethyl benzoateBenzoic acid + C2H4 1
  1963SMI/JON403-405   Benzoic acid, 3-nitro-, ethyl esterC2H4 + 3-Nitrobenzoic acid  788   1.50              1
  Reference reaction:  Ethyl benzoateBenzoic acid + C2H4 1
  1963SMI/JON403-405   Benzoic acid, 3-chloro-, ethyl esterC2H4 + Benzoic acid, 3-chloro-  687   2.77E-04              1
  1963SMI/JON403-405   Benzoic acid, 3-chloro-, ethyl esterC2H4 + Benzoic acid, 3-chloro-  788   1.28              1
  Reference reaction:  Ethyl benzoateBenzoic acid + C2H4 1
  1963SMI/JON403-405   Benzoic acid, 4-bromo-, ethyl esterC2H4 + 4-Bromobenzoic acid  687   2.63E-04              1
  1963SMI/JON403-405   Benzoic acid, 4-bromo-, ethyl esterC2H4 + 4-Bromobenzoic acid  788   1.25              1
  Reference reaction:  Ethyl benzoateBenzoic acid + C2H4 1
  1963SMI/JON403-405   Benzoic acid, 4-chloro-, ethyl esterBenzoic acid, 4-chloro- + C2H4  687   2.42E-03              1
  1963SMI/JON403-405   Benzoic acid, 4-chloro-, ethyl esterBenzoic acid, 4-chloro- + C2H4  788   1.28              1
  Reference reaction:  Ethyl benzoateBenzoic acid + C2H4 1
  1963SMI/JON403-405   Benzoic acid, 3-hydroxy-, ethyl esterC2H4 + Benzoic acid, 3-hydroxy-  788   0.98              1
  Reference reaction:  Ethyl benzoateBenzoic acid + C2H4 1
  1963SMI/JON403-405   Benzoic acid, 3-methoxy-, ethyl esterC2H4 + 3-Methoxybenzoic acid  687   2.41E-03              1
  1963SMI/JON403-405   Benzoic acid, 3-methoxy-, ethyl esterC2H4 + 3-Methoxybenzoic acid  788   1.07              1
  Reference reaction:  Ethyl benzoateBenzoic acid + C2H4 1
  1963SMI/JON403-405   Benzoic acid, 3-bromo-, ethyl esterC2H4 + Benzoic acid, 3-bromo-  687   2.95E-03              1
  1963SMI/JON403-405   Benzoic acid, 3-bromo-, ethyl esterC2H4 + Benzoic acid, 3-bromo-  788   1.27              1
  Reference reaction:  Ethyl benzoateBenzoic acid + C2H4 1
  1963SMI/JON403-405   Benzoic acid, 4-iodo-, ethyl esterC2H4 + Benzoic acid, 4-iodo-  788   1.32              1
  Reference reaction:  Ethyl benzoateBenzoic acid + C2H4 1
  1963SMI/JON403-405   Benzoic acid, 3-iodo-, ethyl esterC2H4 + Benzoic acid, 3-iodo-  788   1.32              1
  Reference reaction:  Ethyl benzoateBenzoic acid + C2H4 1

Search returned 24 records.