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Accessibility information
Author(s):   Teranishi, H.; Benson, S.W.
Title:   The kinetics of dehydrogenation of isobutane by iodine and the heat of formation of the t-butyl radical
Journal:   J. Am. Chem. Soc.
Volume:   85
Year:   1963
Reference type:   Journal article
Squib:   1963TER/BEN2887

Reaction:   tert-C4H9I + Itert-C4H9 + I2
Reaction order:   2
Temperature:   525 - 583 K
Pressure:  0.18 - 0.39 bar
Rate expression:   8.32x10-11 [cm3/molecule s] e-54377 [J/mole]/RT
Bath gas:   iso-C4H10
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
525 3.24E-16
550 5.70E-16
575 9.56E-16
583 1.12E-15