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Accessibility information
Author(s):   Yang, K.
Title:   Free radical reactions initiated by ionizing radiations. III. Paraffin reactivities in hydrogen atom abstraction reactions
Journal:   J. Phys. Chem.
Volume:   67
Year:   1963
Reference type:   Journal article
Squib:   1963YAN562

Reaction:   n-C4H10 + → Other Products + H2
Reaction order:   2
Reference reaction:   CH3CH=CH2 + → Products
Temperature:   300 - 500 K
Rate expression:   1.81x10-11 [cm3/molecule s] (T/298 K)0.50 e-26357 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Ultrasonics
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 4.68E-16
325 1.10E-15
350 2.29E-15
375 4.33E-15
400 7.58E-15
425 1.25E-14
450 1.94E-14
475 2.89E-14
500 4.14E-14