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Accessibility information
Author(s):   Carmichael, H.; Johnston, H.S.
Title:   Correlation of activation energies and bond energies in CF3 reactions
Journal:   J. Chem. Phys.
Volume:   41
Page(s):  
Year:   1964
Reference type:   Journal article
Squib:   1964CAR/JOH1975

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1964CAR/JOH1975   CHCl3 + ·CF3CHF3 + ·CCl3  390 - 523   1.58E-12       2.64E04      2
  1964CAR/JOH1975   CHCl3 + ·CF3CHF3 + ·CCl3  450 - 550   2.01E-11       2.97E04      2
  1964CAR/JOH1975   CH4 + ·CF3CHF3 + ·CH3  357 - 534   1.58E-12       4.61E04      2
  1964CAR/JOH1975   CH3Cl + ·CF3CHF3 + ·CH2Cl  450 - 550   2.01E-11       3.93E04      2
  1964CAR/JOH1975   C3H8 + ·CF3CHF3 + iso-C3H7  450 - 550   2.01E-11       3.43E04      2
  1964CAR/JOH1975   CH2Cl2 + ·CF3CHF3 + CHCl2  450 - 550   2.01E-11       3.43E04      2
  1964CAR/JOH1975   CD4 + ·CF3 → CDF3 + CD3  379 - 560   2.51E-13       5.06E04      2
  1964CAR/JOH1975   CD4 + ·CF3 → CDF3 + CD3  450 - 550   2.01E-11       4.94E04      2
  1964CAR/JOH1975   CCl3D + ·CF3 → CDF3 + ·CCl3  338 - 537   1.00E-12       3.77E04      2
  1964CAR/JOH1975   CCl3D + ·CF3 → CDF3 + ·CCl3  450 - 550   2.01E-11       3.60E04      2
  1964CAR/JOH1975   CD3Cl + ·CF3 → CDF3 + CD2Cl  450 - 550   1.58E-11       4.39E04      2
  1964CAR/JOH1975   CD2Cl2 + ·CF3 → CDF3 + CDCl2  450 - 550   2.01E-11       3.93E04      2
  1964CAR/JOH1975   CH3CD3 + ·CF3 → CDF3 + CH3CD2  450 - 550   2.01E-11       4.10E04      2
  1964CAR/JOH1975   ·CF3 + CH3CD2CH3 → CDF3 + (CH3)2CD·  450 - 550   2.01E-11       3.89E04      2
  1964CAR/JOH1975   ·CF3 + (CH3)3CD → CDF3 + tert-C4H9  334 - 480   5.01E-12       3.09E04      2
  1964CAR/JOH1975   ·CF3 + (CH3)3CD → CDF3 + tert-C4H9  450 - 550   2.01E-11       3.18E04      2

Search returned 16 records.