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Accessibility information
Author(s):   Carmichael, H.; Johnston, H.S.
Title:   Correlation of activation energies and bond energies in CF3 reactions
Journal:   J. Chem. Phys.
Volume:   41
Year:   1964
Reference type:   Journal article
Squib:   1964CAR/JOH1975

Reaction:   CHCl3 + ·CF3CHF3 + ·CCl3
Reaction order:   2
Temperature:   390 - 523 K
Pressure:  2.40E-2 - 8.40E-2 bar
Rate expression:   1.58x10-12 [cm3/molecule s] e-26357 [±2636 J/mole]/RT
Bath gas:   (CF3)2CO
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Direct photolysis
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
390 4.66E-16
400 5.71E-16
425 9.10E-16
450 1.38E-15
475 2.00E-15
500 2.79E-15
523 3.68E-15