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Author(s):   Castellano, E.; Gatti, R.; Sicre, J.E.; Schumacher, H.J.
Title:   Das Gleichgewicht F2S2O6=2 FSO3, das Absorptionsspektrum des Radikals FSO3 und die Kinetik der thermischen Reaktion zwischen Bis-Sulfurylfluoridperoxid und Schwefeltetrafluorid
Journal:   Z. Phys. Chem. (Neue Folge)
Volume:   42
Page(s):   174 - 186
Year:   1964
Reference type:   Journal article
Squib:   1964CAS/GAT174-186

Reaction:   SF4 + F2S2O6 → SF4(FSO3)2
Reaction order:   2
Temperature:   393 - 443 K
Pressure:  6.40E-2 - 0.14 bar
Rate expression:   2.01x10-12 [cm3/molecule s] e-72835 [J/mole]/RT
Bath gas:   F2S2O6
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
393 4.19E-22
400 6.19E-22
425 2.25E-21
443 5.19E-21