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Accessibility information
Author(s):   Herndon, W.C.; Lowry, L.L.
Title:   Mechanism of the pyrolysis of bicyclo[2.2.1]heptadiene. Kinetics of the bicyclo[2.2.1]heptadiene to toluene isomerization
Journal:   J. Am. Chem. Soc.
Volume:   86
Year:   1964
Reference type:   Journal article
Squib:   1964HER/LOW1922

Reaction:   2,5-NorbornadieneToluene
Reaction order:   1
Temperature:   617 - 704 K
Rate expression:   1.7x1014 [s-1] e-221996 [±8314472 J/mole]/RT
Uncertainty:   1.74000001
Bath gas:   2,5-Norbornadiene
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
617 2.73E-5
625 4.76E-5
650 2.46E-4
675 1.13E-3
700 4.63E-3
704 5.75E-3