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Accessibility information
Author(s):   Laidler, K.J.; McKenney, D.J.
Title:   Kinetics and mechanisms of the pyrolysis of diethyl ether. II. The reaction inhibited by nitric oxide
Journal:   Proc. R. Soc. London
Volume:   278
Page(s):   517 - 526
Year:   1964
Reference type:   Journal article
Squib:   1964LAI/MCK517-526

Reaction:   (C2H5)2OC2H5OH + C2H4
Reaction order:   1
Temperature:   833 - 913 K
Pressure:  1.33E-2 - 0.48 bar
Rate expression:   2.75x1018 [s-1] e-350871 [J/mole]/RT
Bath gas:   (C2H5)2O
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
833 2.74E-4
850 7.55E-4
875 3.12E-3
900 1.19E-2
913 2.32E-2