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Author(s):   Thynne, J.C.J.
Title:   Hydrogen and deuterium atom abstraction from O-methyl hydroxylamine and deuterated O-methyl hydroxylamine: Kinetic isotope effect and relative reactivities of the methoxyl and amino groups
Journal:   Trans. Faraday Soc.
Volume:   60
Page(s):   2207 - 2213
Year:   1964
Reference type:   Journal article
Squib:   1964THY2207-2213

Reaction:   (CH3N)2 + ·CH3 → Other Products + CH4
Reaction order:   2
Reference reaction:   ·CH3 + ·CH3C2H6
Temperature:   333 - 468 K
Pressure:  4.00E-2 bar
Rate expression:   1.32x10-13 [cm3/molecule s] e-32593 [±164627 J/mole]/RT
Bath gas:   (CH3N)2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Sensitized photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
333 1.02E-18
350 1.80E-18
375 3.80E-18
400 7.31E-18
425 1.30E-17
450 2.17E-17
468 3.04E-17