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Author(s):   Cafferata, L.F.R.; Kerr, J.A.; Trotman-Dickenson, A.F.
Title:   The reactions of methyl radicals with formamide, N-methyl- and NN-dimethyl-formamide
Journal:   J. Chem. Soc. Faraday Trans. 1
Year:   1965
Reference type:   Journal article
Squib:   1965CAF/KER1386

Reaction:   HCON(CH3)2 + ·CH3 → Other Products + CH4
Reaction order:   2
Reference reaction:   ·CH3 + ·CH3C2H6
Temperature:   393 - 571 K
Pressure:  3.07E-2 - 5.60E-2 bar
Rate expression:   4.17x10-13 [cm3/molecule s] e-34754 [J/mole]/RT
Bath gas:   Acetone
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
393 1.00E-17
400 1.21E-17
425 2.23E-17
450 3.85E-17
475 6.28E-17
500 9.75E-17
525 1.45E-16
550 2.09E-16
571 2.76E-16