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Author(s):   Ferguson, J.M.; Phillips, L.
Title:   Reactions of the isopropoxyl radical. Part I. Pyrolysis of isopropyl nitrite in a static system at 175-200°
Journal:   J. Chem. Soc.
Year:   1965
Reference type:   Journal article
Squib:   1965FER/PHI4416

Reaction:   i-C3H7O + NO(CH3)2CO + HNO
Reaction order:   2
Reference reaction:   i-C3H7OCH3CHO + ·CH3
Reference reaction order:   1
Temperature:   448 - 483 K
Pressure:  4.67E-2 bar
Rate expression:   3.82x10-25 [cm3/molecule] e66931 [J/mole]/RT
Bath gas:   i-C3H7ONO
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule]
448 2.43E-17
450 2.24E-17
475 8.75E-18
483 6.61E-18