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Accessibility information
Author(s):   Gray, P.; Jones, A.
Title:   The attack of methyl radicals on tetradeuterohydrazine
Journal:   J. Chem. Soc. Chem. Commun.
Volume:   15
Year:   1965
Reference type:   Journal article
Squib:   1965GRA/JON360

Reaction:   N2H4 + ·CH3CH4 + NH2NH
Reaction order:   2
Reference reaction:   ·CH3 + N2D4 → Other Products + CH3D
Reference reaction order:   2
Temperature:   383 - 453 K
Pressure:  6.67E-2 bar
Rate expression:   1.28±1.8x10-1 e5853 [±1231 J/mole]/RT
Bath gas:   (CH3N)2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
383 8.04E0
400 7.44E0
425 6.71E0
450 6.12E0
453 6.06E0