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Accessibility information
Author(s):   Modica, A.P.; LaGraff, J.E.
Title:   Decomposition and oxidation of C2F4 behind shock waves
Journal:   J. Chem. Phys.
Volume:   43
Year:   1965
Reference type:   Journal article
Squib:   1965MOD/LAG3383

Reaction:   C2F4·CF2 + ·CF2
Reaction order:   2
Temperature:   1200 - 1800 K
Pressure:  0.22 - 0.42 bar
Rate expression:   2.24x10-7 [cm3/molecule s] (T/298 K)0.50 e-232805 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1200 3.31E-17
1250 8.58E-17
1300 2.07E-16
1350 4.69E-16
1400 1.00E-15
1450 2.03E-15
1500 3.93E-15
1550 7.30E-15
1600 1.30E-14
1650 2.25E-14
1700 3.76E-14
1750 6.11E-14
1800 9.67E-14