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Author(s):   Owen, G.E., Jr.; Pearson, J.M.; Szwarc, M.
Title:   Addition of CF3 radicals. Part 3 - Effect of substituents located on the reaction centre upon the entropy and energy of activation
Journal:   Trans. Faraday Soc.
Volume:   61
Page(s):   1722 - 1734
Year:   1965
Reference type:   Journal article
Squib:   1965OWE/PEA1722-1734

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1965OWE/PEA1722-1734   Benzene + ·CF3 → Adduct  338 - 423   0.84       -1247      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
  1965OWE/PEA1722-1734   C2H2 + ·CF3 → Adduct  338 - 453   8.00       -2087      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
  1965OWE/PEA1722-1734   CH3CCH + ·CF3 → Adduct  338 - 453   7.50       -4598      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
  1965OWE/PEA1722-1734   CF2=CCl2 + ·CF3 → Adduct  338 - 453   0.20       -7109      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
  1965OWE/PEA1722-1734   Cyclohexene + ·CF3 → Adduct  356 - 453   1.20       8813      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
  1965OWE/PEA1722-1734   Pyridine + ·CF3 → Adduct  368 - 453   0.45       -1247      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
  1965OWE/PEA1722-1734   C2F4 + ·CF3 → n-C3F7  338 - 453   0.50       -7949      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
  1965OWE/PEA1722-1734   C2Cl4 + ·CF3 → Adduct  353 - 393   0.80       3342      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
  1965OWE/PEA1722-1734   Cyclopentene + ·CF3 → Adduct  338 - 453   1.20       -1.05E04      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
  1965OWE/PEA1722-1734   (Z)-CHCl=CHCl + ·CF3 → Adduct  338 - 453   0.60       -2087      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
  1965OWE/PEA1722-1734   (E)-CHCl=CHCl + ·CF3 → Adduct  338 - 453   0.40       -5438      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
  1965OWE/PEA1722-1734   Hexafluorobenzene + ·CF3 → Adduct  358 - 453   0.72       7525      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
  1965OWE/PEA1722-1734   2-butyne + ·CF3 → Adduct  338 - 453   2.80       -5438      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
  1965OWE/PEA1722-1734   Phenylacetylene + ·CF3 → Adduct  358 - 453   4.30       -9229      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
  1965OWE/PEA1722-1734   (CH3)2C=C(CH3)2 + ·CF3 → Adduct  338 - 453   0.30       -1.65E04      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
  1965OWE/PEA1722-1734   (Z)-2-C4H8 + ·CF3 → Adduct  338 - 453   0.40       -1.45E04      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
  1965OWE/PEA1722-1734   (E)-2-C4H8 + ·CF3 → Adduct  338 - 453   0.40       -1.45E04      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
  1965OWE/PEA1722-1734   ·CF3 + (Z),(Z)-CH3CH=CHCH=CHCH3 → Adduct  338 - 453   0.50       -1.96E04      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
  1965OWE/PEA1722-1734   ·CF3 + ClC≡CCl → Adduct  338 - 453   1.10       -1.17E04      2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3 → CHF3 + (CH3)2CHC(·)(CH3)2 2
Search returned 19 records.