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Accessibility information
Author(s):   Owen, G.E., Jr.; Pearson, J.M.; Szwarc, M.
Title:   Addition of CF3 radicals. Part 3 - Effect of substituents located on the reaction centre upon the entropy and energy of activation
Journal:   Trans. Faraday Soc.
Volume:   61
Page(s):   1722 - 1734
Year:   1965
Reference type:   Journal article
Squib:   1965OWE/PEA1722-1734

Reaction:   C2Cl4 + ·CF3 → Adduct
Reaction order:   2
Reference reaction:   (CH3)2CHCH(CH3)2 + ·CF3CHF3 + (CH3)2CHC(·)(CH3)2
Reference reaction order:   2
Temperature:   353 - 393 K
Pressure:  0.93 bar
Rate expression:   8.0x10-1 e-3342 [±2104 J/mole]/RT
Uncertainty:   2.0
Bath gas:   (CH3)2CHCH(CH3)2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
353 2.56E-1
375 2.74E-1
393 2.88E-1