Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Tsang, W.
Title:   Decyclization of cyclohexene, 4-methylcyclohexene, and 4-vinylcyclohexene in a single-pulse shock tube
Journal:   J. Chem. Phys.
Volume:   42
Page(s):   1805 - 1809
Year:   1965
Reference type:   Journal article
Squib:   1965TSA1805-1809

Reaction:   4-Vinylcyclohexene1,3-Butadiene + 1,3-Butadiene
Reaction order:   1
Temperature:   900 - 1050 K
Pressure:  0.53 - 1.63 bar
Rate expression:   1.58x1015 [s-1] e-259412 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
900 1.39E0
925 3.55E0
950 8.62E0
975 2.00E1
1000 4.45E1
1025 9.53E1
1050 1.97E2