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Accessibility information
Author(s):   Tucker, B.G.; Whittle, E.
Title:   Reactions of trifluoromethyl radicals with iodine, bromine, and hydrogen bromide
Journal:   Trans. Faraday Soc.
Volume:   61
Page(s):  
Year:   1965
Reference type:   Journal article
Squib:   1965TUC/WHI866

Reaction:   ·CF3 + Br2CF3Br + Br·
Reaction order:   2
Reference reaction:   ·CF3 + HBrCHF3 + Br·
Reference reaction order:   2
Temperature:   328 - 607 K
Pressure:  1.61E-3 bar
Rate expression:   3.78 e9063 [±8314472 J/mole]/RT
Bath gas:   (CF3)2CO
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   IR absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
328 1.05E2
350 8.51E1
375 6.92E1
400 5.77E1
425 4.91E1
450 4.26E1
475 3.75E1
500 3.34E1
525 3.01E1
550 2.74E1
575 2.52E1
600 2.33E1
607 2.28E1