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Accessibility information
Author(s):   Amphlett, J.C.; Whittle, E.
Title:   Reactions of trifluoromethyl radicals with bromine, chlorine and hydrogen chloride
Journal:   Trans. Faraday Soc.
Volume:   62
Page(s):  
Year:   1966
Reference type:   Journal article
Squib:   1966AMP/WHI1662

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1966AMP/WHI1662   ·CF3 + I2CF3I + I  346 - 562   4.32E-12              2
  1966AMP/WHI1662   ·CF3 + HClCHF3 + ·Cl  293 - 478   2.76E-13       2.14E04   4.95E-17  2
  1966AMP/WHI1662   ·CF3 + Br2CF3Br + Br·  451 - 600   3.82E-12       2927      2
  1966AMP/WHI1662   ·CF3 + Br2CF3Br + Br·  451 - 600   13.80       -1.84E04      2
  Reference reaction:  ·CF3 + HClCHF3 + ·Cl 2
  1966AMP/WHI1662   ·CF3 + Cl2CF3Cl + ·Cl  293 - 478   1.28E-11       1.50E04   2.94E-14  2
  1966AMP/WHI1662   ·CF3 + Cl2CF3Cl + ·Cl  293 - 478   44.50       -6228   549  2
  Reference reaction:  ·CF3 + ·CF3C2F6 2
  1966AMP/WHI1662   ·CF3 + Cl2CF3Cl + ·Cl  301 - 463   0.69       8073      2
  Reference reaction:  ·CF3 + Br2CF3Br + Br· 2
  1966AMP/WHI1662   ·CF3 + HBrCHF3 + Br·  293 - 478   9.96E-13       1.21E04   7.42E-15  2

Search returned 8 records.