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Accessibility information
Author(s):   Amphlett, J.C.; Whittle, E.
Title:   Reactions of trifluoromethyl radicals with bromine, chlorine and hydrogen chloride
Journal:   Trans. Faraday Soc.
Volume:   62
Year:   1966
Reference type:   Journal article
Squib:   1966AMP/WHI1662

Reaction:   ·CF3 + Br2CF3Br + Br·
Reaction order:   2
Reference reaction:   ·CF3 + HClCHF3 + ·Cl
Reference reaction order:   2
Temperature:   451 - 600 K
Pressure:  0.53 bar
Rate expression:   1.38x101±1.8 e18375 [±8314472 J/mole]/RT
Bath gas:   HCl
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
451 1.85E3
475 1.45E3
500 1.15E3
525 9.29E2
550 7.67E2
575 6.44E2
600 5.49E2