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Accessibility information
Author(s):   Amphlett, J.C.; Whittle, E.
Title:   Reactions of trifluoromethyl radicals with bromine, chlorine and hydrogen chloride
Journal:   Trans. Faraday Soc.
Volume:   62
Year:   1966
Reference type:   Journal article
Squib:   1966AMP/WHI1662

Reaction:   ·CF3 + Cl2CF3Cl + ·Cl
Reaction order:   2
Reference reaction:   ·CF3 + ·CF3C2F6
Reference reaction order:   2
Temperature:   293 - 478 K
Pressure:  0.11 - 0.53 bar
Rate expression:   4.45x101±1.1x101 e6228 [±83976 J/mole]/RT
Bath gas:   HCl
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
293 5.74E2
300 5.40E2
325 4.46E2
350 3.78E2
375 3.28E2
400 2.89E2
425 2.59E2
450 2.35E2
475 2.15E2
478 2.13E2