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Author(s):   Carlton, T.S.; Steeper, J.R.; Christensen, R.L.
Title:   Rates of hydrogen abstraction from methanol by CF3 radicals
Journal:   J. Phys. Chem.
Volume:   70
Year:   1966
Reference type:   Journal article
Squib:   1966CAR/STE3222

Reaction:   CH3OH + ·CF3 → Other Products + CHF3
Reaction order:   2
Reference reaction:   CD3OD + ·CF3 → Other Products + CDF3
Reference reaction order:   2
Temperature:   388 - 527 K
Pressure:  1.12E-2 - 9.55E-2 bar
Rate expression:   8.3x10-1 e7358 [±221 J/mole]/RT
Bath gas:   (CF3N)2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
388 8.12E0
400 7.58E0
425 6.66E0
450 5.93E0
475 5.35E0
500 4.87E0
525 4.48E0
527 4.45E0