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Accessibility information
Author(s):   Clark, T.C.; Clyne, M.A.A.; Stedman, D.H.
Title:   Mechanism of formation of triatomic molecules in atomic combination reactions. Part 1. - Formation of ClNO and ClCO in reactions of atomic chlorine
Journal:   Trans. Faraday Soc.
Volume:   62
Page(s):   3354 - 3365
Year:   1966
Reference type:   Journal article
Squib:   1966CLA/CLY3354-3365

Reaction:   NO + ClNOCl
Reaction order:   3
Temperature:   270 - 620 K
Pressure:  1.33E-3 bar
Rate expression:   9.65x10-32 [±1.35x10-32 cm6/molecule2 s] e5014 [±856 J/mole]/RT
Bath gas:   SF6
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Chemiluminescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
270 9.01E-31
275 8.65E-31
300 7.20E-31
325 6.17E-31
350 5.40E-31
375 4.82E-31
400 4.36E-31
425 3.99E-31
450 3.69E-31
475 3.43E-31
500 3.22E-31
525 3.04E-31
550 2.89E-31
575 2.75E-31
600 2.64E-31
620 2.55E-31