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Accessibility information
Author(s):   Coomber, J.W.; Whittle, E.
Title:   Bromination of fluoro-alkanes. Part 3.-Methane, fluoroform and fluoro-ethanes
Journal:   Trans. Faraday Soc.
Volume:   62
Year:   1966
Reference type:   Journal article
Squib:   1966COO/WHI1553

Reaction:   CF3CH2F + Br·HBr + CF3CHF
Reaction order:   2
Reference reaction:   CH2F2 + Br··CHF2 + HBr
Reference reaction order:   2
Temperature:   403 - 595 K
Pressure:  0.13 - 0.17 bar
Rate expression:   1.65±1.2x10-1 e-12139 [±244 J/mole]/RT
Bath gas:   CF3CH2F
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
403 4.41E-2
425 5.32E-2
450 6.43E-2
475 7.63E-2
500 8.90E-2
525 1.02E-1
550 1.16E-1
575 1.30E-1
595 1.42E-1