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Title: Bromination of fluoro-alkanes. Part 3.-Methane, fluoroform and fluoro-ethanes
Journal: Trans. Faraday Soc.
Volume: 62
Page(s):
Year: 1966
Reference type: Journal article
Squib: 1966COO/WHI1553
Reaction:
C2F5H + Br· → C2F5 + HBr
Reaction order:
2
Reference reaction:
CH4 + Br· → ·CH3 + HBr
Reference reaction order:
2
Temperature:
419 - 559
K
Pressure: 0.13 - 0.17 bar
Rate expression:
8.49x10-2±7.6x10-3 e-1962 [±333 J/mole]/RT
Bath gas:
C2F5H
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 419 | 4.83E-2 |
| 425 | 4.87E-2 |
| 450 | 5.03E-2 |
| 475 | 5.17E-2 |
| 500 | 5.30E-2 |
| 525 | 5.42E-2 |
| 550 | 5.53E-2 |
| 559 | 5.57E-2 |