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Accessibility information
Author(s):   Elliott, C.S.; Frey, H.M.
Title:   Theoretical treatment of the pressure dependence of the unimolecular rate constant. Part 1. Cyclobutene, 1-methylcyclobutene and 3-methylcyclobutene
Journal:   Trans. Faraday Soc.
Volume:   62
Page(s):   895 - 909
Year:   1966
Reference type:   Journal article
Squib:   1966ELL/FRE895-909

Reaction:   Cyclobutene1,3-Butadiene
Reaction order:   1
Temperature:   415 - 430 K
Rate expression:   1.22x1013 [s-1] e-135526 [J/mole]/RT
Bath gas:   1,3-Butadiene
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
415 1.07E-4
425 2.69E-4
430 4.20E-4