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Accessibility information
Author(s):   Gray, P.; Herod, A.A.; Jones, A.; Thynne, J.C.J.
Title:   Kinetics of hydrogen and deuterium atom abstraction by methyl radicals from hydrazines and substituted hydrazines
Journal:   Trans. Faraday Soc.
Volume:   62
Page(s):  
Year:   1966
Reference type:   Journal article
Squib:   1966GRA/HER2774

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1966GRA/HER2774   (CH3)2NND2 + ·CH3 → (CH3)2NN(D)· + CH3D  385 - 448   3.55E-13       2.85E04      2
  1966GRA/HER2774   (CH3)2NND2 + ·CH3 → ·CH2N(CH3)ND2 + CH4  385 - 448   1.48E-13       5.02E04      2
  1966GRA/HER2774   (CH3)2NNH2 + ·CH3 → Other Products + CH4  383 - 443   4.57E-13       2.49E04      2
  1966GRA/HER2774   (CH3)2NNH2 + ·CH3CH4 + Hydrazyl, 2,2-dimethyl-  385 - 448   3.24E-13       2.40E04      2
  1966GRA/HER2774   CH3NHNH2 + ·CH3 → Other Products + CH4  359 - 454   8.14E-15       7209      2
  1966GRA/HER2774   N2H4 + ·CH3CH4 + NH2NH  383 - 453   1.66E-13       2.10E04      2
  1966GRA/HER2774   (CH3N)2 + ·CH3CH4 + ·CH2N=NCH3  383 - 448   1.18E-13       3.32E04      2
  1966GRA/HER2774   CH3NH-NHCH3 + ·CH3 → Other Products + CH4  352 - 435   2.62E-14       1.04E04      2
  1966GRA/HER2774   CH3NH-NHCH3 + ·CH3 → CH3NHN(·)CH3 + CH4  353 - 433   1.38E-14       8896      2
  1966GRA/HER2774   ·CH3 + Hydrazine-1,2-d2, 1,2-dimethyl- → CH3NDN(·)CH3 + CH3D  353 - 453   1.66E-14       1.21E04      2
  1966GRA/HER2774   ·CH3 + Hydrazine-1,2-d2, 1,2-dimethyl- → ·CH2NDNDCH3 + CH4  353 - 453   6.61E-13       2.76E04      2
  1966GRA/HER2774   ·CH3 + N2D4 → ND2ND· + CH3D  383 - 453   1.20E-13       2.68E04      2

Search returned 12 records.