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Accessibility information
Author(s):   Olschewski, H.A.; Troe, J.; Wagner, H.Gg.
Title:   Untersuchung unimolekularer Reaktionen bei hohen Drucken in Stosswellen: Zerfall von CS2 und CO2
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   70
Page(s):   1060 - 1064
Year:   1966
Reference type:   Journal article
Squib:   1966OLS/TRO1060-1064

Reaction:   CS2CS + S
Reaction order:   1
Temperature:   1950 - 2800 K
Pressure:  25.33 - 50.66 bar
Rate expression:   3.98x1012 [s-1] e-364174 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Other (IR)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1950 7.00E2
2000 1.23E3
2050 2.09E3
2100 3.48E3
2150 5.65E3
2200 8.98E3
2250 1.40E4
2300 2.14E4
2350 3.20E4
2400 4.72E4
2450 6.85E4
2500 9.80E4
2550 1.38E5
2600 1.92E5
2650 2.64E5
2700 3.59E5
2750 4.82E5
2800 6.40E5