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Accessibility information
Author(s):   Olschewski, H.A.; Troe, J.; Wagner, H.Gg.
Title:   Untersuchung unimolekularer Reaktionen bei hohen Drucken in Stosswellen: Zerfall von CS2 und CO2
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   70
Page(s):   1060 - 1064
Year:   1966
Reference type:   Journal article
Squib:   1966OLS/TRO1060-1064

Reaction:   CO2CO +
Reaction order:   2
Temperature:   2800 - 4400 K
Pressure:  0.25 bar
Rate expression:   8.32x10-10 [cm3/molecule s] e-414061 [±12389 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Other (IR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
2800 1.57E-17
2900 2.90E-17
3000 5.14E-17
3100 8.78E-17
3200 1.45E-16
3300 2.32E-16
3400 3.62E-16
3500 5.50E-16
3600 8.17E-16
3700 1.19E-15
3800 1.69E-15
3900 2.37E-15
4000 3.26E-15
4100 4.42E-15
4200 5.90E-15
4300 7.77E-15
4400 1.01E-14