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©NIST, 2013
Accessibility information
Author(s):   Singh, H.; Tedder, J.M.
Title:   Free-radical substitution in aliphatic compounds. Part XIV. The halogenation of esters of butan-1-ol
Journal:   J. Chem. Soc. B
Page(s):  
Year:   1966
Reference type:   Journal article
Squib:   1966SIN/TED608

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1966SIN/TED608   CH3COO(CH2)3CH3 + ·ClHCl + CH3C(O)OCH(·)CH2CH2CH3  313 - 433   1.66E-12       3758      2
  1966SIN/TED608   CH3COO(CH2)3CH3 + ·ClHCl + CH3C(O)OCH2CH(·)CH2CH3  313 - 433   2.62E-11       2087      2
  1966SIN/TED608   CH3COO(CH2)3CH3 + ·ClHCl + CH3C(O)OCH2CH2CH(·)CH3  313 - 433   3.32E-11       1247      2
  1966SIN/TED608   CH3COO(CH2)3CH3 + ·ClHCl + CH3C(O)OCH2CH2CH2CH2·  313 - 433   1.32E-11       2927      2
  1966SIN/TED608   CF3C(O)O(CH2)3CH3 + Br·HBr + CF3C(O)OCH(·)CH2CH2CH3  296 - 517   2.09E-12       4.35E04   5.00E-20  2
  1966SIN/TED608   CF3C(O)O(CH2)3CH3 + Br·HBr + CF3C(O)OCH2CH(·)CH2CH3  296 - 517   4.17E-11       4.86E04   1.29E-19  2
  1966SIN/TED608   CF3C(O)O(CH2)3CH3 + Br·HBr + CF3C(O)OCH2CH2CH(·)CH3  296 - 517   6.61E-11       4.27E04   2.21E-18  2
  1966SIN/TED608   CF3C(O)O(CH2)3CH3 + Br·HBr + CF3C(O)OCH2CH2CH2CH2  296 - 517   4.17E-11       5.56E04   7.42E-21  2
  1966SIN/TED608   CF3C(O)O(CH2)3CH3 + ·ClHCl + CF3C(O)OCH(·)CH2CH2CH3  324 - 457   5.25E-12       4182      2
  1966SIN/TED608   CF3C(O)O(CH2)3CH3 + ·ClHCl + CF3C(O)OCH2CH2CH(·)CH3  324 - 457   3.32E-11       1247      2
  1966SIN/TED608   CF3C(O)O(CH2)3CH3 + ·ClHCl + CF3C(O)OCH2CH2CH2CH2  324 - 457   1.66E-11       2927      2
  1966SIN/TED608   CF3C(O)OC(CH3)3 + ·ClHCl + CF3C(O)OCH2CH(·)CH2CH3  324 - 457   1.66E-11       2087      2
  1966SIN/TED608   HCOO(CH2)3CH3 + ·Cl → HC(O)OCH2CH2CH(·)CH3 + HCl  313 - 423   3.32E-10       1247      2
  1966SIN/TED608   HCOO(CH2)3CH3 + ·Cl → HC(O)OCH2CH2CH2CH2· + HCl  313 - 423   1.24E-11       2503      2
  1966SIN/TED608   HCOO(CH2)3CH3 + ·ClHCl + HC(O)OCH2CH(·)CH2CH3  313 - 423   1.05E-11       1247      2

Search returned 15 records.