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Accessibility information
Author(s):   Singh, H.; Tedder, J.M.
Title:   Free-radical substitution in aliphatic compounds. Part XIV. The halogenation of esters of butan-1-ol
Journal:   J. Chem. Soc. B
Year:   1966
Reference type:   Journal article
Squib:   1966SIN/TED608

Reaction:   CF3C(O)O(CH2)3CH3 + Br·HBr + CF3C(O)OCH2CH(·)CH2CH3
Reaction order:   2
Temperature:   296 - 517 K
Pressure:  3.33E-2 bar
Rate expression:   4.17x10-11 [cm3/molecule s] e-48557 [J/mole]/RT
Bath gas:   CF3C(O)O(CH2)3CH3
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
296 1.13E-19
300 1.46E-19
325 6.55E-19
350 2.36E-18
375 7.19E-18
400 1.90E-17
425 4.49E-17
450 9.63E-17
475 1.91E-16
500 3.53E-16
517 5.18E-16