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Author(s):   Tedder, J.M.; Watson, R.A.
Title:   Free-radical substitution in aliphatic compounds. Part XVI. The reaction of methyl radicals with n-butane
Journal:   J. Chem. Soc. B
Year:   1966
Reference type:   Journal article
Squib:   1966TED/WAT1069

Reaction:   n-C4H10 + ·CH3CH4 + sec-C4H9
Reaction order:   2
Reference reaction:   n-C4H10 + ·CH3CH4 + n-C4H9
Reference reaction order:   2
Temperature:   371 - 492 K
Pressure:  0.29 - 0.32 bar
Rate expression:   1.21x102 e6901 [±414 J/mole]/RT
Bath gas:   n-C4H10
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
371 1.13E3
375 1.11E3
400 9.64E2
425 8.53E2
450 7.65E2
475 6.94E2
492 6.54E2