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Accessibility information
Author(s):   Tomkinson, D.M.; Pritchard, H.O.
Title:   Abstraction of halogen atoms by methyl radicals
Journal:   J. Phys. Chem.
Volume:   70
Page(s):  
Year:   1966
Reference type:   Journal article
Squib:   1966TOM/PRI1579

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1966TOM/PRI1579   CCl4 + ·CH3CH3Cl + ·CCl3  363 - 418   4.17E-11       5.40E04      2
  1966TOM/PRI1579   CCl3CCl3 + ·CH3CH3Cl + C2Cl5  363 - 418   1.05E-12       4.22E04      2
  1966TOM/PRI1579   CCl3CCl3 + ·CH3CH3Cl + C2Cl5  403   0.70              2
  Reference reaction:  CCl4 + ·CH3CH3Cl + ·CCl3 2
  1966TOM/PRI1579   CH2I2 + ·CH3CH3I + ·CH2I  403   2800              2
  Reference reaction:  CCl4 + ·CH3CH3Cl + ·CCl3 2
  1966TOM/PRI1579   iso-C3H7I + ·CH3CH3I + iso-C3H7  403   270              2
  Reference reaction:  CCl4 + ·CH3CH3Cl + ·CCl3 2
  1966TOM/PRI1579   CF2Br2 + ·CH3CH3Br + CBrF2  363 - 418   1.66E-13       2.68E04      2
  1966TOM/PRI1579   CF2Br2 + ·CH3CH3Br + CBrF2  403   13.00              2
  Reference reaction:  CCl4 + ·CH3CH3Cl + ·CCl3 2
  1966TOM/PRI1579   CCl3Br + ·CH3CH3Br + ·CCl3  363 - 418   2.62E-11       2.97E04      2
  1966TOM/PRI1579   CCl3Br + ·CH3CH3Br + ·CCl3  403   1000              2
  Reference reaction:  CCl4 + ·CH3CH3Cl + ·CCl3 2
  1966TOM/PRI1579   CF3Br + ·CH3CH3Br + ·CF3  363 - 418   3.32E-11       5.23E04      2
  1966TOM/PRI1579   CF3Br + ·CH3CH3Br + ·CF3  403   2.00              2
  Reference reaction:  CCl4 + ·CH3CH3Cl + ·CCl3 2
  1966TOM/PRI1579   CFCl3 + ·CH3CH3Cl + ·CCl2F  403   0.10              2
  Reference reaction:  CCl4 + ·CH3CH3Cl + ·CCl3 2
  1966TOM/PRI1579   CFCl2CF2Cl + ·CH3 → Other Products + CH3Cl  403   0.10              2
  Reference reaction:  CCl4 + ·CH3CH3Cl + ·CCl3 2
  1966TOM/PRI1579   Trichloromethyl benzene + ·CH3 → Dichloromethyl, phenyl- + CH3Cl  363 - 418   3.32E-14       3.18E04      2
  1966TOM/PRI1579   Trichloromethyl benzene + ·CH3 → Dichloromethyl, phenyl- + CH3Cl  403   0.50              2
  Reference reaction:  CCl4 + ·CH3CH3Cl + ·CCl3 2
  1966TOM/PRI1579   n-C3H7I + ·CH3CH3I + 1-C3H7  403   140              2
  Reference reaction:  CCl4 + ·CH3CH3Cl + ·CCl3 2
  1966TOM/PRI1579   2-Propanone, 1,1,1,3,3,3-hexachloro- + ·CH3CH3Cl + CCl3C(O)CCl2·  363 - 418   6.61E-12       4.06E04      2
  1966TOM/PRI1579   2-Propanone, 1,1,1,3,3,3-hexachloro- + ·CH3CH3Cl + CCl3C(O)CCl2·  403   5.00              2
  Reference reaction:  CCl4 + ·CH3CH3Cl + ·CCl3 2
  1966TOM/PRI1579   C2Cl4 + ·CH3CH3Cl + CCl2=CCl  403   0.10              2
  Reference reaction:  CCl4 + ·CH3CH3Cl + ·CCl3 2
  1966TOM/PRI1579   CF2BrCl + ·CH3 → Products  403   17.00              2
  Reference reaction:  CCl4 + ·CH3CH3Cl + ·CCl3 2
  1966TOM/PRI1579   CCl3CN + ·CH3 → Products  363 - 418   1.32E-11       4.35E04      2
  1966TOM/PRI1579   CCl3CN + ·CH3 → Products  403   7.00              2
  Reference reaction:  CCl4 + ·CH3CH3Cl + ·CCl3 2
  1966TOM/PRI1579   CBr4 + ·CH3CH3Br + CBr3  363 - 418   2.62E-10       3.31E04      2
  1966TOM/PRI1579   CBr4 + ·CH3CH3Br + CBr3  403   4300              2
  Reference reaction:  CCl4 + ·CH3CH3Cl + ·CCl3 2
  1966TOM/PRI1579   Iodobenzene + ·CH3CH3I + Phenyl  403   1.50              2
  Reference reaction:  CCl4 + ·CH3CH3Cl + ·CCl3 2
  1966TOM/PRI1579   CCl2Br2 + ·CH3 → Products  363 - 418   1.05E-10       3.18E04      2
  1966TOM/PRI1579   CCl2Br2 + ·CH3 → Products  403   2300              2
  Reference reaction:  CCl4 + ·CH3CH3Cl + ·CCl3 2
  1966TOM/PRI1579   ·CH3 + CF3I → Products  363 - 418   1.05E-12       3.13E04      2
  1966TOM/PRI1579   ·CH3 + CF3I → Products  403   2150              2
  Reference reaction:  CCl4 + ·CH3CH3Cl + ·CCl3 2

Search returned 29 records.