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Accessibility information
Author(s):   Amphlett, J.C.; Whittle, E.
Title:   Reactions of trifluoromethyl radicals with iodine and hydrogen iodide
Journal:   Trans. Faraday Soc.
Volume:   63
Year:   1967
Reference type:   Journal article
Squib:   1967AMP/WHI2695

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1967AMP/WHI2695   CHF3 + H2 + ·CF3  350 - 600   5.31E-12       4.69E04      2
  1967AMP/WHI2695   CHF3 + SH·CF3 + H2S  350 - 600   1.83E-12       7.99E04      2
  1967AMP/WHI2695   CF3Br + Br··CF3 + Br2  350 - 600   1.08E-10       1.01E05      2
  1967AMP/WHI2695   CF3Cl + ·Cl·CF3 + Cl2  350 - 600   3.16E-10       1.31E05      2
  1967AMP/WHI2695   ·CF3 + I2CF3I + I  346 - 562   4.85       -2129      2
  Reference reaction:  ·CF3 + HICHF3 + I 2
  1967AMP/WHI2695   ·CF3 + HICHF3 + I  346 - 562   8.97E-13       2087      2
  1967AMP/WHI2695   CF3I + I·CF3 + I2  350 - 600   1.23E-10       7.45E04      2

Search returned 7 records.