Kinetics Database Resources

Other Databases

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...

Administrative Links

NIST home page

MML home page

Chemical Sciences Division

Home
©NIST, 2020
Accessibility information

Author(s):   Cillien, C.; Goldfinger, P.; Huybrechts, G.; Martens, G.
Title:   Hydrogen abstraction from chlorinated ethanes by chlorine atoms
Journal:   Trans. Faraday Soc.
Volume:   63
Page(s):   1631 - 1635
Year:   1967
Reference type:   Journal article
Squib:   1967CIL/GOL1631-1635

Associated entries:

Search Results

Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |

Squib	Reaction	Temp [K]	A	Ea [J/mole]	k(298.00 K)	Order
1967CIL/GOL1631-1635	CH₃CCl₃ + ·Cl → HCl + CCl₃CH₂	323 - 423	4.17E-12	1.50E04		2
1967CIL/GOL1631-1635	CH₃CCl₃ + ·Cl → HCl + CCl₃CH₂	323 - 423	0.07	1247		2
Reference reaction: CH₃Cl + ·Cl → ·CH₂Cl + HCl					2
1967CIL/GOL1631-1635	C₂H₅Cl + ·Cl → HCl + CH₂CH₂Cl	323 - 423	1.48E-10	4390		2
1967CIL/GOL1631-1635	C₂H₅Cl + ·Cl → HCl + CH₃CHCl	323 - 423	5.89E-11	6269		2
1967CIL/GOL1631-1635	C₂H₅Cl + ·Cl → HCl + CH₃CHCl	323 - 423	3.16			2
Reference reaction: C₂H₅Cl + ·Cl → HCl + CH₂CH₂Cl					2
1967CIL/GOL1631-1635	CH₃CHCl₂ + ·Cl → HCl + CH₃CCl₂·	323 - 423	1.48E-11	7949		2
1967CIL/GOL1631-1635	CH₃CHCl₂ + ·Cl → HCl + CHCl₂CH₂·	323 - 423	1.66E-11	1.42E04		2
1967CIL/GOL1631-1635	CH₃CHCl₂ + ·Cl → HCl + CHCl₂CH₂·	323 - 423	0.28	416		2
Reference reaction: CH₃Cl + ·Cl → ·CH₂Cl + HCl					2
1967CIL/GOL1631-1635	CH₃CHCl₂ + ·Cl → HCl + CHCl₂CH₂·	323 - 423	1.12	6269		2
Reference reaction: CH₃CHCl₂ + ·Cl → HCl + CH₃CCl₂·					2
1967CIL/GOL1631-1635	CHCl₂CCl₃ + ·Cl → C₂Cl₅ + HCl	323 - 423	7.42E-12	1.49E04		2
1967CIL/GOL1631-1635	CHCl₂CCl₃ + ·Cl → C₂Cl₅ + HCl	323 - 423	0.63	831		2
Reference reaction: CHCl₃ + ·Cl → ·CCl₃ + HCl					2
1967CIL/GOL1631-1635	CHCl₂CH₂Cl + ·Cl → HCl + CHCl₂CHCl	323 - 423	2.34E-11	1.55E04		2
1967CIL/GOL1631-1635	CHCl₂CH₂Cl + ·Cl → HCl + CHCl₂CHCl	323 - 423	2.00	1463		2
Reference reaction: CHCl₃ + ·Cl → ·CCl₃ + HCl					2
1967CIL/GOL1631-1635	CHCl₂CH₂Cl + ·Cl → HCl + CHCl₂CHCl	323 - 423	1.58	2503		2
Reference reaction: CHCl₂CH₂Cl + ·Cl → HCl + CH₂ClCCl₂·					2
1967CIL/GOL1631-1635	CHCl₂CH₂Cl + ·Cl → HCl + CH₂ClCCl₂·	323 - 423	1.48E-11	1.30E04		2
1967CIL/GOL1631-1635	(CHCl₂)2 + ·Cl → HCl + CHCl₂C(·)Cl₂	323 - 423	0.50	3758		2
Reference reaction: CHCl₃ + ·Cl → Products					2
1967CIL/GOL1631-1635	(CHCl₂)2 + ·Cl → HCl + CHCl₂C(·)Cl₂	323 - 423	5.89E-12	1.02E04		2
1967CIL/GOL1631-1635	CH₂ClCH₂Cl + ·Cl → HCl + CH₂ClCHCl·	323 - 423	1.05E-10	1.30E04		2
1967CIL/GOL1631-1635	CH₂ClCH₂Cl + ·Cl → HCl + CH₂ClCHCl·	323 - 423	1.78	-831		2
Reference reaction: CH₃Cl + ·Cl → ·CH₂Cl + HCl					2
1967CIL/GOL1631-1635	CH₂ClCCl₃ + ·Cl → HCl + CCl₃CHCl	323 - 423	2.34E-12	1.02E04		2
1967CIL/GOL1631-1635	CH₂ClCCl₃ + ·Cl → HCl + CCl₃CHCl	323 - 423	0.20	-3758		2
Reference reaction: CHCl₃ + ·Cl → ·CCl₃ + HCl					2

Search returned 21 records.