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Author(s):   Cillien, C.; Goldfinger, P.; Huybrechts, G.; Martens, G.
Title:   Hydrogen abstraction from chlorinated ethanes by chlorine atoms
Journal:   Trans. Faraday Soc.
Volume:   63
Page(s):   1631 - 1635
Year:   1967
Reference type:   Journal article
Squib:   1967CIL/GOL1631-1635

Reaction:   CH2ClCH2Cl + ClHCl + CH2ClCHCl·
Reaction order:   2
Reference reaction:   CH3Cl + Cl·CH2Cl + HCl
Reference reaction order:   2
Temperature:   323 - 423 K
Pressure:  0.40 - 1.29 bar
Rate expression:   1.78 e831 [±1039 J/mole]/RT
Uncertainty:   1.40999997
Bath gas:   H2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
323 2.43E0
325 2.42E0
350 2.37E0
375 2.32E0
400 2.29E0
423 2.25E0