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Author(s):   Cvetanovic, R.J.; Irwin, R.S.
Title:   Rates of addition of methyl radicals to olefins in the gas phase
Journal:   J. Chem. Phys.
Volume:   46
Year:   1967
Reference type:   Journal article
Squib:   1967CVE/IRW1694

Reaction:   (E)-2-C4H8 + ·CH3 → Other Products + CH4
Reaction order:   2
Reference reaction:   iso-C4H10 + ·CH3 → Other Products + CH4
Reference reaction order:   2
Temperature:   353 - 453 K
Pressure:  3.04 - 4.05 bar
Rate expression:   3.4 e-2677 [J/mole]/RT
Bath gas:   iso-C4H10
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
353 1.37E0
375 1.44E0
400 1.52E0
425 1.59E0
450 1.66E0
453 1.67E0