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Author(s):   Dijkestra, A.J.; Kerr, J.A.; Trotman-Dickenson, A.F.
Title:   Reactions of difluoroamino-radicals. Part IV. Addition to vinyl halides
Journal:   J. Chem. Soc. A
Year:   1967
Reference type:   Journal article
Squib:   1967DIJ/KER864

Reaction:   CH2CH(NF2)Br → CH2=CHBr + NF2
Reaction order:   1
Reference reaction:   NF2 + CH2CH(NF2)Br → F2NCH2CHBrNF2
Reference reaction order:   2
Temperature:   351 - 405 K
Rate expression:   4.78x1022 [molecule/cm3] e-47725 [J/mole]/RT
Bath gas:   N2F4
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [molecule/cm3]
351 3.78E15
375 1.08E16
400 2.80E16
405 3.34E16