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Accessibility information
Author(s):   Kerr, J.A.; Lloyd, A.C.
Title:   Kinetics and pressure dependence of the decomposition of the propionyl radical
Journal:   Trans. Faraday Soc.
Volume:   63
Page(s):   2480 - 2488
Year:   1967
Reference type:   Journal article
Squib:   1967KER/LLO2480-2488

Reaction:   CH3CH2COCO + ·C2H5
Reaction order:   1
Temperature:   303 - 353 K
Pressure:  2.27E-2 - 0.18 bar
Rate expression:   2.09x1013 [s-1] e-61527 [J/mole]/RT
Bath gas:   H2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
303 5.17E2
325 2.70E3
350 1.37E4
353 1.64E4