Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Olschewski, H.A.; Troe, J.; Wagner, H.GG.
Title:   Studies of unimolecular reactions of triatomic molecules
Journal:   Symp. Int. Combust. Proc.
Volume:   11
Year:   1967
Reference type:   Journal article
Squib:   1967OLS/TRO155

Reaction:   CO2CO +
Reaction order:   1
Temperature:   2800 - 3500 K
Rate expression:   2.0x1011 [s-1] e-464779 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
2800 4.27E2
2850 6.06E2
2900 8.50E2
2950 1.18E3
3000 1.62E3
3050 2.19E3
3100 2.95E3
3150 3.93E3
3200 5.18E3
3250 6.78E3
3300 8.80E3
3350 1.13E4
3400 1.45E4
3450 1.84E4
3500 2.32E4