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©NIST, 2013
Accessibility information
Author(s):   Peel, T.E.; Rye, R.T.B.
Title:   Formation of carbon monoxide in the pyrolysis of N-alkylchloroacetamides
Journal:   Chem. Commun.
Page(s):   184 - 186
Year:   1967
Reference type:   Journal article
Squib:   1967PEE/RYE184-186

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1967PEE/RYE184-186   CH3C(O)NHC(CH3)3 → Other Products + iso-C4H8  627   37.00              1
  Reference reaction:  CH3C(O)NHC(CH3)3 → Other Products + CO 1
  1967PEE/RYE184-186   CH3C(O)NHC(CH3)3 → Other Products + CO  627   1.00E-07              1
  1967PEE/RYE184-186   CH2ClC(O)NC(CH3)3 → Other Products + iso-C4H8  627   2.00              1
  Reference reaction:  CH2ClC(O)NC(CH3)3 → Other Products + CO 1
  1967PEE/RYE184-186   CH2ClC(O)NC(CH3)3 → Other Products + CO  627   2.80E-06              1
  1967PEE/RYE184-186   CCl3C(O)NC(CH3)3 → Other Products + CO  627   2.80E-05              1
  1967PEE/RYE184-186   CHCl2C(O)NC(CH3)3 → Other Products + iso-C4H8  627   1.00              1
  Reference reaction:  CHCl2C(O)NC(CH3)3 → Other Products + CO 1
  1967PEE/RYE184-186   CHCl2C(O)NC(CH3)3 → Other Products + CO  627   5.30E-05              1

Search returned 7 records.