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Accessibility information
Author(s):   Quee, M.J.Y.; Thynne, J.C.J.
Title:   The photolysis of organic enters
Journal:   Int. Conf. Photochem. Prepr. 1967
Page(s):   283 - 303
Year:   1967
Reference type:   Journal article
Squib:   1967QUE/THY283-303

Reaction:   CH3OCOOCH3 + CH3 → Other Products + CH3OH
Reaction order:   2
Temperature:   303 - 376 K
Rate expression:   9.3x10-14 [cm3/molecule s] e-24694 [J/mole]/RT
Bath gas:   CH3OCOOCH3
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
303 5.15E-18
325 9.99E-18
350 1.92E-17
375 3.38E-17
376 3.45E-17