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Accessibility information
Author(s):   Tedder, J.M.; Walton, J.C.
Title:   Free radical addition to olefins. Part 3.-Addition of trichloromethyl radicals to propene, 2-fluoropropene and hexafluoropropene
Journal:   Trans. Faraday Soc.
Volume:   63
Year:   1967
Reference type:   Journal article
Squib:   1967TED/WAL2678

Reaction:   CH3CH=CH2 + ·CCl3CHCl3 + ·CH2CH=CH2
Reaction order:   2
Temperature:   332 - 483 K
Rate expression:   1.66x10-12 [cm3/molecule s] e-26357 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
332 1.18E-16
350 1.94E-16
375 3.54E-16
400 6.00E-16
425 9.57E-16
450 1.45E-15
475 2.10E-15
483 2.34E-15