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Accessibility information
Author(s):   Thomas, P.J.
Title:   Kinetics of the thermal decomposition of 3-chlorobut-1-ene and 3-chloro-2-methylbut-1-ene
Journal:   J. Chem. Soc. B
Page(s):   1238 - 1241
Year:   1967
Reference type:   Journal article
Squib:   1967THO1238-1241

Reaction:   1-Butene, 3-chloro-2-methyl-CH2=C(CH3)CH=CH2 + HCl
Reaction order:   1
Temperature:   593 - 633 K
Pressure:  9.07E-2 - 0.49 bar
Rate expression:   1.9x1013 [s-1] e-196222 [J/mole]/RT
Bath gas:   1-Butene, 3-chloro-2-methyl-
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
593 9.88E-5
600 1.57E-4
625 7.58E-4
633 1.22E-3