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Title: Kinetics of the thermal decomposition of 3-chlorobut-1-ene and 3-chloro-2-methylbut-1-ene
Journal: J. Chem. Soc. B
Page(s): 1238 - 1241
Year: 1967
Reference type: Journal article
Squib: 1967THO1238-1241
Reaction:
1-Butene, 3-chloro-2-methyl- → CH2=C(CH3)CH=CH2 + HCl
Reaction order:
1
Temperature:
593 - 633
K
Pressure: 9.07E-2 - 0.49 bar
Rate expression:
1.9x1013 [s-1] e-196222 [J/mole]/RT
Bath gas:
1-Butene, 3-chloro-2-methyl-
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 593 | 9.88E-5 |
| 600 | 1.57E-4 |
| 625 | 7.58E-4 |
| 633 | 1.22E-3 |